kristash7ir9agh
kristash7ir9agh kristash7ir9agh
  • 11-04-2016
  • Chemistry
contestada

What is the pH of an aqueous 0.032 M pyridine, (C5H5N)? (Kb for pyridine = 1.7 x 10–9)

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Willchemistry
Willchemistry Willchemistry
  • 11-04-2016
pH + H₂O ⇋ [pOH]⁺ + OH⁻
 
Kb = [pOH⁺][OH⁻] / [ pH] = 1.7×10⁻⁹

Let x mol dissociate:

 [pOH
⁺] = [OH⁻] = x [pH] = 0.032 - x ≈ 0.032

[x] [x] / [0.032] = 1.7×10⁻⁹

x₂ = 0.032 * 1.7 x 10⁻⁹

x = 5.44 x 10⁻¹¹ = [OH⁻] 

pOH = -log [OH⁻] = -log[  5.44 x 10⁻¹¹] = 10.26

pH = 14.00 - pOH 

pH = 14.00 -  10.26

PH = 3.74

hope this helps!
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